Promoter-Induced Reactive Phase Separation in Surface Reactions

Promoter-induced reactive phase separation in surface reactions.

Promoters are adsorbed mobile species which do not directly participate in a catalytic surface reaction, but can influence its rate. Often, they are characterized by strong attractive interactions with one of the reactants. We show that these conditions lead to a Turing instability of the uniform state and to the formation of reaction-induced periodic concentration patterns. Experimentally such...

Phase-Separation-Induced Surface Patterns in Thin Polymer Blend Films

Atomic force microscopy (AFM), neutron reflection (NR) and secondary ion mass spectroscopy (SIMS) are used to examine phase separation in symmetrically segregating thin polymer blend films (e1000 Å). Phase separation in the film leads to undulations of the liquid-air interface, provided the film is sufficiently thin to suppress surface-directed spinodal decomposition waves. Flattened droplets a...

Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment

Drying Induced Phase Separation

Phase separation simulation study related to cellulose acetate-water-acetone has been done. Results show that porous asymmetric and symmetric membranes can be produced by changing the nonsolvent concentration or by the drying conditions without altering the polymer content using dry-casting process. Dry-casting process is the process in which complete evaporation of solvent and nonsolvent takes...

Motility-Induced Phase Separation

Self-propelled particles include both self-phoretic synthetic colloids and various micro-organisms. By continually consuming energy, they bypass the laws of equilibrium thermodynamics. These laws enforce the Boltzmann distribution in thermal equilibrium: the steady state is then independent of kinetic parameters. In contrast, self-propelled particles tend to accumulate where they move more slow...